Publication

In Press

・Radical Polymerization of Vinyl Boronate Involving Backbiting Chain Transfer and Post-Polymerization Oxidation Affording Branched Poly(vinyl alcohol)s
Kanazawa, T.; Nishikawa, T.*; Ouchi, M.*
ChemRxiv (preprint), 2024, DOI:10.26434/chemrxiv-2024-5cxxm

・Lamellar Microphase Separation and Phase Transition of Hydrogen-Bonding/Crystalline Statistical Copolymers: Amide Functionalization at the Interface
Ikami, T.; Aoki, H.; Terashima, T.*
ACS Macro. Lett., 2024, Accepted.

・Design of sec-Benzyl Vinyl Ethers toward the Synthesis of Alternating Copolymers Composed of Vinyl Alcohol and Vinyl Ether Units
Kubota, H.; Ouchi, M.*
ACS Macro. Lett., 2024, Accepted.

2024

・Umpolung Isomerization in Radical Copolymerization of Benzyl Vinyl Ether with Pentafluorophenylacrylate Leading to Degradable AAB Periodic Copolymers
Kuroda, K.; Ouchi, M.*
Angew. Chem., Int. Ed., 2023, 63(1), e202316875.

2023

・Microphase Separation of Cationic Homopolymers Bearing Alkyl Ammonium Salts into Sub-4 nm Lamellar Materials with Water Intercalation Channels
Sujita, R.; Imai, S.; Ouchi, M.; Aoki, H.; Terashima, T.*
Macromolecules, 2023, 56(23), 9738–9749.

・Polymer Degradation by Synergistic Dual Stimuli: Base Interaction and Photocatalysis to Unlock a Boron Pendant Trigger for Main-Chain Scission
Makino, H.; Nishikawa, T.*; Ouchi, M.*
Macromolecules, 2023, 56(21), 8776–8783.

・Radical Cyclocopolymerization of a Transformable Divinyl Monomer with a Monovinyl Monomer and Postpolymerization Modification for the Synthesis of AAB-Type Alternating Copolymers Composed of NIPAM and Vinyl Ether
Xu, X.; Ouchi, M.*
Macromolecules, 2023, 56(19), 7950–7960.

・Hydration State on Poly(ethylene glycol)-Bearing Homopolymers and Random Copolymer Micelles: In Relation to the Thermoresponsive Property and Micellar Structure
Hishida, H.*; Kanno, R.; Terashima, T.*
Macromolecules, 2023, 56(18), 7587–7596.

・Self-Assembly of Amphiphilic Alternating Copolymers by Chain Folding in Water: From Uniform Composition and Sequence to Monodisperse Micelles
Kono, H.; Hibino, M.; Ida, D.; Ouchi, M.; Terashima, T.*
Macromolecules, 2023, 56(15), 6086–6098.

・Stereospecific Radical Polymerization of a Side-Chain Transformable Bulky Acrylamide Monomer and Subsequent PPM for Syntheses of Isotactic Polyacrylate and Polyacrylamide
Pan, Y.; Ouchi, M.*
Angew. Chem., Int. Ed., 2023, 62(35), e202308855.
Selected as a “Hot Paper”

・Photocatalyzed Hydrogen Atom Transfer Degradation of Vinyl Polymers: Cleavage of a Backbone C−C Bond Triggered by Radical Activation of a C−H Bond in a Pendant
Kimura, T.; Ouchi, M.*
Angew. Chem., Int. Ed., 2023, 62(33), e202305252.

・Synthesis of Methacrylic Acid-Acrylonitrile Alternating Copolymer Using an Extremely Bulky Methacrylate and the Sequence-Dependent Thermal Reaction Behaviors
Oh, D.; Ouchi, M.*
Eur. Polym. J., 2023, 193, 112063.
Selected as a cover

・Dynamic Exchange of Amphiphilic Random Copolymers between Micelles in Water: Kinetics and Mechanism Analyzed by TR-SANS
Hibino, M.; Tanaka, S.; Hiroi, K.; Aoki, H.; Hiroi, K.;Terashima, T.*
Macromolecules, 2023, 56(8), 2955–2964.

・Micelle-crosslinked hydrogels with stretchable, self-healing, and selectively adhesive properties: Random copolymers work as dynamic yet self-sorting domains
Asai, H.; Shibata, M.; Takenaka, M.; Takata, S.; Hiroi, K.; Ouchi, M.; Terashima, T.*
Aggregate, 2023, 4(3), e316.

・Self-assembly and salt-induced thermoresponsive properties of amphiphilic PEG/cation random terpolymers in water
Kanno, R.; Ouchi, M.; Terashima, T.*
Polym. Chem., 2023, 14(15), 1718–1726.
Selected as a front cover

・ビニルボロン酸誘導体の連鎖重合化学：ホウ素を活かすモノマー設計と側鎖置換による重合後変換
西川剛*, 大内誠*
有機合成化学協会誌, 2023, 81(4), 313–323.

　※有機合成化学協会の非会員の方はこちらから閲覧可能 (転載許諾済み)

・A Transformable and Bulky Methacrylate Monomer That Enables the Synthesis of an MMA-nBA Alternating Copolymer: Sequence-Dependent Self-Healing Properties
Lai, H.; Jin, C.; Park, J.; Ikura, R.; Takashima, Y.; Ouchi, M.*
Angew. Chem., Int. Ed., 2023, 62(14), e202218597.
Selected as a "Hot Paper."

・Rapid and Selective Photo-degradation of Polymers: Design of an Alternating Copolymer with an o-Nitrobenzyl Ether Pendant
Kubota, H.; Ouchi, M.*
Angew. Chem., Int. Ed., 2023, 62(7), e202217365.

・Precision Syntheses of Poly(NIPAM-alt-HEMA) and Effects of Alternating Sequence on Thermoresponsive Behaviors in Water
Xu, X.; Shibata, K.; Ouchi, M.*
Polym. Chem., 2023, 14(1), 55–61.

2022

・Anthranilamide-Protected Vinyl Boronic Acid: Rational Monomer Design for Improved Polymerization/ Transformation Ability Providing Access to Conventionally Inaccessible Copolymers
Suzuki, H.; Nishikawa, T.*; Makino, H.; Ouchi, M.*
Chem. Sci., 2022, 13(43), 12703–12712.
Selected as 2022 Chemical Science HOT Article

・Water-Assisted Microphase Separation of Cationic Random Copolymers into Sub-5 nm Lamellar Materials and Thin Films
Imai, S.; Arakawa, M.; Nakanishi, Y.; Takenaka, M.; Aoki, H.; Ouchi, M.; Terashima, T.*
Macromolecules, 2022, 55(20), 9113–9125.

・Incorporation of boryl pendant as the trigger in methacrylate polymer for backbone degradation
Makino, H.; Nishikawa, T.*; Ouchi, M.*
Chem. Commun., 2022, 58(85), 11957-11960.

・ホウ素の特性を活用した新規ビニルモノマーの開拓　-重合後変換による自在な高分子合成を目指して-
西川剛
化学と工業, 2022, 75(9), 659-660.

・Reversible Co-Self-Assembly and Self-Sorting Systems of Polymer Micelles in Water: Polymers Switch Association Partners in Response to Salts
Kanno, R.; Tanaka, K.; Ikami, T.; Ouchi, M.; Terashima, T.*
Macromolecules, 2022, 55(12), 5213–5221.

・Copolymerizations of Saccharin Methacrylamide with Dienes toward Softer Alternating Copolymers and Advanced Sequence Control
Kametani, Y.; Ouchi, M.*
Macromol. Chem. Phys., 2022, 223(12), 2100249
Selected as a back cover

・Homopolymer-block-Alternating Copolymers Composed of Acrylamide Units: Design of Transformable Divinyl Monomers and Sequence-Specific Thermoresponsive Properties
Shibata, K.; Kametani, Y.; Daito, Y.; Ouchi, M.*
J. Am. Chem. Soc., 2022, 144(22), 9959–9970.

・Orthogonal C–B Bond Transformation as an Approach for Versatile Synthesis of End-Functionalized Polymers
Kanazawa, T.; Nishikawa, T.*; Ouchi, M.*
ACS Macro Lett., 2022, 11(5), 706–710.

・Precise Syntheses of Alternating Cyclocopolymers via Radical Copolymerizations of Divinyl Ether with N-Substituted Maleimides
Kubota, H.; Ouchi, M.*
Macromolecules, 2022, 55(10), 4025–4033.
Selected as a front cover

・Long-Range Ordered Lamellar Formation with Lower Molecular Weight PS-PMMA Block Copolymers: Significant Effects of Discrete Oligopeptides at the Junction
Yoshimura, T.; Morishita, T.; Agata, Y.; Nagashima, K.; Wylie, K.; Nabae, Y.; Hayakawa, T.*; Ouchi, M.*
Macromolecules, 2022, 55(6), 2148–2159.
Press release from Kyoto University
Selected as a supplementary cover

・Amphiphilic Random-Block Copolymer Micelles in Water: Precise and Dynamic Self-Assembly Controlled by Random Copolymer Association
Hibino, M.; Tanaka, K.; Ouchi, M.; Terashima, T.*
Macromolecules, 2022, 55(1), 178–189.

2021

・Multilayered Lamellar Materials and Thin Films by Instant Self-Assembly of Amphiphilic Random Copolymers
Ikami, T.; Watanabe, Y.; Ogawa,H.; Takenaka, M.; Yamada, L, N.; Ouchi, M.; Aoki, H.*; Terashima, T.*
ACS Macro Lett., 2021, 10(12), 1524–1528.
Selected as a supplementary cover.

・Metal-Catalyzed Switching Degradation of Vinyl Polymers via Introduction of an “In-Chain” Carbon–Halogen Bond as the Trigger
Kimura, T.; Kuroda, K.; Kubota, H.; Ouchi, M.*
ACS Macro Lett., 2021, 10(12), 1535–1539.
Selected as a supplementary cover.

・Backbone-Degradable Polymers via Radical Copolymerizations of Pentafluorophenyl Methacrylate with Cyclic Ketene Acetal: Pendant Modification and Efficient Degradation by Alternating-Rich Sequence
Lai, H.; Ouchi, M.*
ACS Macro Lett., 2021, 10(10), 1223–1228.

・RAFT polymerization of isopropenyl boronate pinacol ester and subsequent terminal olefination: precise synthesis of poly(alkenyl boronate)s and evaluation of their thermal properties
Kanazawa, T.; Nishikawa, T.*; Ouchi, M.*
Polym. J., 2021, 53(11), 1167–1174.
Assist. Prof. Nishikawa was selected as Rising Stars in Polymer Science 2021.

・Cation Template-Assisted RAFT Cyclopolymerization of Hexa(Ethylene Glycol) Di(meth)acrylates to Thermoresponsive Pseudo-Crown Ether Polymers
Kimura, Y.; Terashima, T.*
Macromol. Rapid., Commun. 2021, 42(18), 2000670.
Selected as a front cover.

・Ouzo phase occurrence with alternating lipo/hydrophilic copolymers in water
Trevisan, H.; Nishimori, K.; Aime, S.; Guigner, J.-M.; Ouchi, M.; Tournilhac, F.*
Soft Matter, 2021, 17(31), 7384–7395.

・One-Pot Preparation of Methacrylate/Styrene Alternating Copolymers via Radical Copolymerization and Alcoholysis Modification: Sequence Impacts on Glass Transition Temperature
Kametani, Y.; Ouchi, M.*
ACS Polym. Au, 2021, 1(1), 10–15.
Selected as a supplementary cover.
ACS Polymers Au’s Most Viewed Papers in 2021.

・Vinylboronic acid pinacol ester as a vinyl alcohol-precursor monomer in radical copolymerizations with styrene
Makino, H.; Nishikawa, T.*; Ouchi, M.*
Chem. Commun., 2021, 57(60), 7410–7413.

・Thermoresponsive Gelation of Amphiphilic Random Copolymer Micelles in Water
Shibata, M.; Terashima, T.*; Koga, T.*
Macromolecules, 2021, 54(11), 5241–5248.

・Amphiphilic Random Cyclocopolymers as Versatile Scaffolds for Ring-Functionalized and Self-Assembled Materials
Kimura, Y.; Imai, S.; Takenaka, M.; Terashima, T.*
Macromolecules, 2021, 54(9), 3987–3998.

・Construction of ring-based architectures via ring-expansion cationic polymerization and post-polymerization modification: design of cyclic initiators from divinyl ether and dicarboxylic acid
Kusuyama, N.; Daito, Y.; Kubota, H.; Kametani, Y.; Ouchi, M.*
Polym. Chem., 2021, 12(17), 2532–2541.
Selected as a back cover.

・Design guide of amphiphilic crystalline random copolymers for sub-10 nm microphase separation
Ikami, T.; Kimura, Y.; Takenaka, M.; Ouchi, M.; Terashima, T.*
Polym. Chem., 2021, 12(4), 501–510.
Selected as a back cover.

・Magnesium bromide (MgBr2) as a catalyst for living cationic polymerization and ring-expansion cationic polymerization
Daito, Y.; Kojima, R.; Kusuyama, N.; Kohsaka, Y.; Ouchi, M.*
Polym. Chem., 2021, 12(5), 702–710.

・Amphiphilic random and random block terpolymers with PEG, octadecyl, and oleyl pendants for controlled crystallization and microphase separation
Imai, S.; Ommura, Y.; Watanabe, Y.; Ogawa, H.; Takenaka, M.; Ouchi, M.; Terashima, T.*
Polym. Chem., 2021, 12(10), 1432–1439.
Selected as an inside front cover.

・Recent Development in Polymer Reactions for Overcoming Synthetic Limitations in Chain-Growth Polymerization (Highlight Review)
Nishikawa, T.; Ouchi, M.*
Chem. Lett., 2021, 50, 411-417.
Selected as an inside cover.

・Construction methodologies and sequence-oriented properties of sequence-controlled oligomers/polymers generated via radical polymerization
Ouchi, M.*
Polym. J., 2021,53(2) 239–248.

2020

・Morphology transition of amphiphilic homopolymer self-assemblies in water triggered by pendant design and chain length
Kimura, Y.; Terashima, T.*
Eur. Polym. J., 2020, 139, 110001.

・Saccharin-Pendant Methacrylamide as a Unique Monomer in Radical Copolymerization: Peculiar Alternating Copolymerization with Styrene
Kametani, Y.; Ouchi, M.*
Polym. Chem., 2020, 11(40), 6505–6511.

・Alternating Copolymers of Vinyl Catechol or Vinyl Phenol with Alkyl Maleimide for Adhesive and Water-Repellent Coating Materials
Nishimori,K.; Tenjimbayashi, M.; Naito, M.*; Ouchi, M.*
ACS Appl. Polym. Mater., 2020, 2(11), 4604–4612.

・Single-chain crosslinked polymers via the transesterification of folded polymers: from efficient synthesis to crystallinity control
Ito,D.; Kimura, Y.; Takenaka, M.; Ouchi, M.; Terashima, T.*
Polym. Chem., 2020, 11(32), 5181–5190.

・Folded amphiphilic homopolymer micelles in water: uniform self-assembly beyond amphiphilic random copolymers
Kimura, Y.; Ouchi, M.; Terashima, T.*
Polym. Chem., 2020, 11(32), 5156–5162.
Selected as an inside front cover.

・Controlled Self-Assembly of Amphiphilic Random Copolymers into Folded Micelles and Nanostructure Materials
Terashima, T.*
Journal of Oleo Science, 2020, 69(6), 529–538.

・両親媒性ランダムコポリマーの自己組織化
寺島崇矢
自己修復材料、自己組織化、形状記憶材料の開発と応用事例, 2020, 303–313.

・Self-Sorting of Amphiphilic Block-Pendant Homopolymers into Sphere or Rod Micelles in Water
Kimura, Y.; Takenaka, M.; Ouchi, M.; Terashima, T.*
Macromolecules, 2020, 53(12), 4942–4951.

・Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement
Makino, H.; Nishikawa, T.*; Ouchi, M.*
ACS Macro Lett., 2020, 9(6), 788–793.

・Ring-Expansion Cationic Cyclopolymerization for Construction of Cyclic Cyclopolymers
Kubota, H.; Yoshida, S.; Ouchi, M.*
Polym. Chem., 2020, 11(24), 3964–3971.
Selected as an inside front cover.

・二種類のモノマー単位が交互につながった高分子 -環化重合による交互シークエンス共重合体の合成と配列機能-
大内誠
化学, 2020, 75(6), 68-69.

・モノマー単位を高分子鎖内で精密に混ぜる -配列制御で拓く新しい高分子材料-
大内誠
化学と工業, 2020, 73(5), 399-401.

・Design of a maleimide monomer to achieve precise sequence control and functionalization for an alternating copolymer with vinylphenol
Nishimori, K.; Ouchi, M.*
Polym. J., 2020, 52(7), 717–729.

・Selective Coupling and Polymerization of Folded Polymer Micelles to Nanodomain Self-Assemblies
Ommura, Y.; Imai, S.; Takenaka, M.; Ouchi, M.; Terashima, T.*
ACS Macro Lett., 2020, 9(3), 426–430.
Selected as a front cover.

・AB-alternating copolymers via chain-growth polymerization: synthesis, characterization, self-assembly, and functions
Nishimori, K.; Ouchi, M.*
Chem. Commun., 2020, 56(24), 3473–3483.
Selected as an inside cover.

・Unprecedented Sequence Control and Sequence‐Driven Properties in A Series of AB‐Alternating Copolymers Consisting Solely of Acrylamide Units
Kametani, Y.; Tournilhac, F.; Sawamoto, M.; Ouchi, M.*
Angew. Chem. Int. Ed., 2020, 59(13), 5193–5201.
Press release from Kyoto University
Press release from JST

・Molecular Imprinting on Amphiphilic Folded Polymers for Selective Molecular Recognition in Water
Nagao, C.; Sawamoto, M.; Terashima, T.*
J. Polym. Sci., 2020, 58(1), 215–224.

2019

・Unusual Radical Copolymerization of Suprabulky Methacrylate with N-Hydroxysuccinmide Acrylate: Facile Syntheses of Alternating-Rich Copolymers of Methacrylic Acid and N-Alkyl Acrylamide
Oh, D.; Furuya, Y.; Ouchi, M.*
Macromolecules, 2019, 52(22), 8577–8586.

・両親媒性ランダム共重合体の自己組織化
寺島崇矢
高分子, 2019, 68(9), 493-494.

・Self-assembly of amphiphilic block pendant polymers as microphase separation materials and folded flower micelles
Matsumoto, M.; Takenaka, M.; Sawamoto, M.; Terashima, T.*
Polym. Chem., 2019, 10(36), 4954–4961.

・Controlled radical depolymerization of chlorine-capped PMMA via reversible activation of the terminal group by ruthenium catalyst
Sano, Y.; Konishi, T.; Sawamoto, M.; Ouchi, M.*
Eur. Polym. J., 2019, 120, 109181.

・Polymethacrylic Acid Shows Thermoresponsivity in an Organic Solvent
Cazares-Cortes, E.; Baker, C. B.; Nishimori, K.; Ouchi, M.; Tournilhac, F.*
Macromolecules, 2019, 52(15), 5995–6004.

・Design of Thermoresponsive Polymers Toward Antibody Purification
Nishimori, K.; Maruyama, M.*; Shimazaki, Y.*; Ouchi, M.*; Yoshida, H.
ACS Appl. Polym. Mater., 2019, 1(8), 1925–1929.
Selected as a cover picture.

・An Alkenyl Boronate as a Monomer for Radical Polymerizations: Boron as a Guide for Chain Growth and as a Replaceable Side Chain for Post‐Polymerization Transformation
Nishikawa, T.; Ouchi, M.*
Angew. Chem. Int. Ed., 2019, 58(36), 12435–12439.
Selected as a "Hot Paper."

・Physical gelation of AB-alternating copolymers made of vinyl phenol and maleimide units: cooperation between precisely incorporated phenol and long alkyl pendant groups
Nishimori, K.; Cazares-Cortes, E.; Guigner, J.-M.; Tournilhac, F.*; Ouchi, M.*
Polym. Chem., 2019, 10(18), 2327–2336.

・Orthogonal Folding of Amphiphilic/Fluorous Random Block Copolymers for Double and Multicompartment Micelles in Water
Matsumoto, M.; Sawamoto, M.; Terashima, T.*
ACS Macro Lett., 2019, 8(3), 320–325.

・Precise control of single unit monomer radical addition with a bulky tertiary methacrylate monomer toward sequence-defined oligo- or poly(methacrylate)s via the iterative process
Oh, D.; Sawamoto, M.; Ouchi, M.*
Polym. Chem., 2019, 10(16), 1998–2003.
Selected as a cover picture.
Selected as the paper of the month.

・Self-Sorting of Amphiphilic Copolymers for Self-Assembled Materials in Water: Polymers Can Recognize Themselves
Imai, S.; Takenaka, M.; Sawamoto, M.; Terashima, T.*
J. Am. Chem. Soc., 2019, 141(1), 511–519.

・Amphiphilic Fluorous Random Copolymer Self-Assembly for Encapsulation of a Fluorinated Agrochemical
Ko, H. J.; Bhattacharya, A.; Terashima, T.*; Sawamoto, M.; Maynard, D. H.*
J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 532–539.

・Design of Maleimide Monomer for Higher Level of Alternating Sequence in Radical Copolymerization with Styrene
Nishimori, K.; Sawamoto, M.; Ouchi, M.*
J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 367–375.

2018

・環拡大カチオン重合による環状ポリマーの精密合成
大内誠
環状高分子の合成と機能発現, 監修：手塚育志, シーエムシー出版, 2018, pp. 47–56.

・配列制御ポリマーと環状ポリマーの精密合成：配列とトポロジーが温度応答性に与える影響
大内誠
刺激応答性高分子ハンドブック, 監修：宮田隆志, シーエムシー出版, 2018, pp. 49–54.

・ランダム共重合体を基盤とするミセル構築とナノ構造体の創出
寺島崇矢
ブロック共重合体の構造制御と応用展開, 監修：竹中幹人, シーエムシー出版, 2018, pp. 101–116.

・原子移動ラジカル重合によるシークエンス制御
大内誠
リビングラジカル重合 −機能性高分子の合成と応用展開−, 監修：松本章一, シーエムシー出版, 2018, pp. 18–26.

・リビングラジカル重合による両親媒性ポリマーの合成と精密ナノ会合体の創出
寺島崇矢
リビングラジカル重合 −機能性高分子の合成と応用展開−, 監修：松本章一, シーエムシー出版, 2018, pp. 146–157.

・Control of Alternating Sequence for N-isopropylacrylamide (NIPAM) and Methacrylic Acid (MAA) Units in Copolymer via Cyclopolymerization and Transformation of the Cyclopendant
Kametani, Y.; Sawamoto, M.; Ouchi, M.*
Angew. Chem. Int. Ed., 2018, 57(34), 10905–10909.
Press release from Kyoto University.

・Self-Assembly of Amphiphilic ABA Random Triblock Copolymers in Water
Kozawa,K. S.; Matsumoto, K.; Suzuki, A.; Sawamoto, M.; Terashima, T.*
J. Polym. Sci. Part A: Polym. Chem., 2018, 57, 313–321.

・Acrylate-Selective Transesterification of Methacrylate/Acrylate Copolymers: Postfunctionalization with Common Acrylates and Alcohols
Ito, D.; Ogura, Y.; Sawamoto, M.; Terashima, T.*
ACS Macro Lett., 2018, 7(8), 997–1002.

・Programmed Self-Assembly of Amphiphilic Random Copolymers in Water via Controlled Radical Polymerization
Terashima, T.*
ACS Symp. Ser., 2018, 1285, 143–155.

・Nanostructured Materials via the Pendant Self-Assembly of Amphiphilic Crystalline Random Copolymers
Hattori, G.; Takenaka, M.; Sawamoto, M.; Terashima, T.*
J. Am. Chem. Soc., 2018, 140(27), 8376–8379.

・Intramolecular Folding or Intermolecular Self-Assembly of Amphiphilic Random Copolymers: On-Demand Control by Pendant Design
Shibata, M.; Matsumoto, M.; Hirai, Y.; Takenaka, M.; Sawamoto, M.; Terashima, T.*
Macromolecules, 2018, 51(10), 3738–3745.

・Fluorous Gradient Copolymers via in-Situ Transesterification of a Perfluoromethacrylate in Tandem Living Radical Polymerization: Precision Synthesis and Physical Properties
Ogura, Y.; Takenaka, M.; Sawamoto, M.; Terashima, T.*
Macromolecules, 2018, 51(3), 864–871.

・Programmed Self-Assembly Systems of Amphiphilic Random Copolymers into Size-Controlled and Thermoresponsive Micelles in Water
Imai, S.; Hirai, Y.; Nagao, C.; Sawamoto, M.; Terashima, T.*
Macromolecules, 2018, 51(2), 398–409.

・Sequence Regulation in Chain-Growth Polymerizations
Ouchi, M.
Wiley, Lutz, J.-F. (ed), Sequence‐Controlled Polymers, 2018, pp 257–279.

・Sequence-controlled polymers via reversible-deactivation radical polymerization
Ouchi, M.*; Sawamoto, M.
Polym. J., 2018, 50(1), 83–94.

2017

・Expanding vinyl ether monomer repertoire for ring‐expansion cationic polymerization: Various cyclic polymers with tailored pendant groups
Kammiyada, H.; Ouchi, M.*; Sawamoto, M.*
J. Polym. Sci. Part A: Polym. Chem. 2017, 55(18), 3082-3089.

・Fluorous Comonomer Modulates the Reactivity of Cyclic Ketene Acetal and Degradation of Vinyl Polymers
Ko, H, J.; Terashima, T.*; Sawamoto, M.; Maynard, D. H.*
Macromolecules, 2017, 50(23), 9222-9232.

・Self-assembly of PEG/dodecyl-graft amphiphilic copolymers in water: consequences of the monomer sequence and chain flexibility on uniform micelles
Hattori, G.; Hirai, Y.; Sawamoto, M.; Terashima, T.*
Polym. Chem., 2017, 8(46), 7248-7259.

・Cyclopolymerization of Cleavable Acrylate-Vinyl Ether Divinyl Monomer via Nitroxide-Mediated Radical Polymerization: Copolymer beyond Reactivity Ratio
Kametani, Y.; Nakano, M.; Yamamoto, T.; Ouchi, M.*; Sawamoto, M.
ACS Macro Lett., 2017, 6, 754−757.

・Self-Folding Polymer Iron Catalysts for Living Radical Polymerization
Azuma, Y.; Terashima, T.*; Sawamoto, M.*
ACS Macro Lett., 2017, 6, 830-835.

・Single-Chain Nanoparticles via Self-Folding Amphiphilic Copolymers in Water
Terashima, T.; Sawamoto, M.
Wiley, Pomposo, J. A. (ed), Single-Chain Polymer Nanoparticles: Synthesis, Characterization, Simulations and Applications, 2017, pp 313-339.

・両親媒性ランダムコポリマーの自己組織化：一次構造制御による精密ナノ会合体の創出
寺島崇矢、澤本光男
高分子論文集, 2017, 74(4), 265-277.

・Self-Assembly of Amphiphilic Random Copolyacrylamides into Uniform and Necklace Micelles in Water
Kimura, Y.; Terashima, T.*; Sawamoto, M.*
Macromol. Chem. Phys., 2017, 218(18), 1700230.

・Compartmentalization Technologies via Self-Assembly and Cross-Linking of Amphiphilic Random Block Copolymers in Water
Matsumoto, M.; Terashima, T.*; Matsumoto, K.; Takenaka, M.; Sawamoto, M.*
J. Am. Chem. Soc. 2017, 139, 7164-7167.

・Synthesis of Fluorinated Gradient Copolymers via In Situ Transesterification with Fluoroalcohols in Tandem Living Radical Polymerization
Ogura, Y.; Terashima, T.*; Sawamoto, M.*
Polym. Chem., 2017, 8, 2299-2308. (Inside Front Cover)

・Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification
Ogura, Y.; Artar, M.; Palmans, A. R. A.; Sawamoto, M.*; Meijer, E. W.; Terashima, T.*
Macromolecules, 2017, 50, 3215-3223.

・Microgel Star Polymer Catalysts as Active and Functional Nanoreactors for Organic Reactions and Polymerizations
Terashima, T.; Sawamoto, M.
Springer, Poli (ed), Effects of Nanoconfinement on Catalysis, Fundamental and Applied Catalysis, 2017, 125-146.

・A Study on Physical Properties of Cyclic Poly(vinyl ether)s Synthesized via Ring-Expansion Cationic Polymerization
Kammiyada, H.; Ouchi, M.*; Sawamoto, M.*
Macromolecules, 2017, 50, 841-848.

・Amphiphilic PEG-Functionalized Gradient Copolymers via Tandem Catalysis of Living Radical Polymerization and Transesterification
Ogura, Y.; Terashima, T.*; Sawamoto, M.*
Macromolecules, 2017, 50, 822-831.

・Precision Synthesis of Imine-Functionalized Reversible Microgel Star Polymers via Dynamic Covalent Cross-Linking of Hydrogen-Bonding Block Copolymer Micelles
Azuma, Y.; Terashima, T.*; Sawamoto, M.*
Macromolecules, 2017, 50, 587-596.

2016

・リビングラジカル重合をすべての人に
寺島崇矢
化学, 2016, 71(12), 62-63

・Periodic Introduction of Hamilton Receptor into Polystyrene Backbone for Supramolecular Graft Copolymer with Regular Interval
Lee, S.; Ouchi, M.*; Kim, S.; Sawamoto, M.*
Polym. Chem., 2016, 7, 7152-7160.

・Amphiphilic Random Copolymers with Hydrophobic/Hydrogen- Bonding Urea Pendants: Self-Folding Polymers in Aqueous and Organic Media
Matsumoto, K.; Terashima, T.*; Sugita, T.; Takenaka, M.; Sawamoto, M.*
Macromolecules, 2016, 49, 7917−7927.

・A Convergent Approach to Ring Polymers with Narrow Molecular Weight Distributions through Post Dilution in Ring Expansion Cationic Polymerization
Kammiyada, H.; Ouchi, M.*; Sawamoto, M.*
Polym. Chem., 2016, 7, 6911-6917.

・Alternating Sequence Control for Carboxylic Acid and Hydroxy Pendant Groups via Controlled Radical Cyclopolymerization of a Divinyl Monomer Carrying a Cleavable Spacer
Ouchi, M.*; Nakano, M.; Nakanishi, T.; Sawamoto, M.*
Angew. Chem. Int. Ed., 2016, DOI: 10.1002/ange.201607169

・Ferrocene Cocatalysis for Ruthenium-Catalyzed Radical Miniemulsion Polymerization
Bultz, E.; Ouchi, M.*; Fujimura, K.; Sawamoto, M.*; Cunningham, M. F.*
Polymer, 2016, DOI: 10.1016/j.polymer.2016.08.084

・Living CO2-Switchable Latexes Prepared via Emulsion ATRP and AGET Miniemulsion ATRP
Su, X.; Nishizawa, K.; Bultz, E.; Sawamoto, M.; Ouchi, M.; Jessop, P.G.*; Cunningham, M. F.*
Macromolecules, 2016, 49, 6251-6259.

・Sequence Analysis for Alternating Copolymers by MALDI‐TOF‐MS: Importance of Initiator Selectivity for Comonomer Pair
Nishimori, K.; Ouchi, M.*; Sawamoto, M.*
Macromol. Rapid. Commun., 2016, 37, 1414–1420.
Selected as Back Cover

・精密ラジカル重合による機能性高分子
寺島崇矢、澤本光男
高分子, 2016, 65(9), 503-505

・Polyacrylamide Pseudo Crown Ethers via Hydrogen Bond-Assisted Cyclopolymerization
Kimura,Y.; Miyabara, Y.; Terashima, T.*; Sawamoto, M.*
J. Polym. Sci. Part A: Polym. Chem. 2016, 54, 3294-3302.

・Precision Self-Assembly of Amphiphilic Random Copolymers into Uniform and Self-Sorting Nanocompartments in Water
Hirai, Y.; Terashima, T.*; Takenaka, M.; Sawamoto, M.*
Macromolecules 2016, 49, 5084-5091.

・Protein Storage with Perfluorinated PEG Compartments in a Hydrofluorocarbon Solvent
Koda, Y.; Terashima, T.*; Maynard. H. D.; Sawamoto, M.*
Polym. Chem. 2016, 7, 6694-6698.

・Multimode Self-Folding Polymers via Reversible and Thermoresponsive Self-Assembly of Amphiphilic/Fluorous Random Copolymers
Koda, Y.; Terashima, T.*; Sawamoto, M.*
Macromolecules 2016, 49, 4534-4543.

・Iterative Radical Addition with a Special Monomer Carrying Bulky and Convertible Pendant: A New Concept toward Controlling the Sequence for Vinyl Polymers
Oh, D.; Ouchi, M.*; Nakanishi, T.; Ono, H.; Sawamoto, M.*
ACS Macro Lett. 2016, 5, 745-749.

・Terminal-Selective Transesterification of Chlorine-Capped Poly(Methyl Methacrylate)s: A Modular Approach to Telechelic and Pinpoint-Functionalized Polymers
Ogura, Y.; Terashima, T.*; Sawamoto, M.*
J. Am. Chem. Soc. 2016, 138, 5012-5015.

・Cationic Cp*–Ruthenium Catalysts for Metal-Catalyzed Living Radical Polymerization: Cocatalyst-Independent Catalysis Tuned by Counteranion
Fujimura, K.; Ouchi, M.*; Tsujita, J.; Sawamoto, M.*
Macromolecules 2016, 49, 2962-2970.

・A Strategy for Sequence Control in Vinyl Polymers via Iterative Controlled Radical Cyclization
Hibi, Y.; Ouchi, M.*; Sawamoto, M.*
Nature Commun. 2016, 7, 11064.(DOI: 10.1038/ncomms11064.) プレス1(JST) プレス2(京都大学) 紹介記事

・Design of a hydrophilic ruthenium catalyst for metal-catalyzed living radical polymerization: highly active catalysis in water
Nishizawa, K.; Ouchi, M.*; Sawamoto, M.*
RSC Adv. 2016, 6, 6577-6582.

・Discussion on “Aperiodic Copolymers”
Rowan, S.J.*; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Robert B Grubbs, R.B.; Hillmyer, M.A.; Hutchings, L.R., Mahanthappa, M. K.; Moatsou, D.; O’Reilly, R.K.; Ouchi, M.; Sawamoto, M.; Lodge, T.P.*
ACS Macro Lett. 2016, 5, 1–3.

・リビング重合とは：総論
澤本光男
CSJ カレントレビュー精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 14-19.

・ラジカル重合（２）：金属触媒
大内誠
CSJ カレントレビュー精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 63-74.

・星型ポリマー
金岡鐘局，寺島崇矢
CSJ カレントレビュー精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 144-152.

・連鎖制御ポリマー
大内誠
CSJ カレントレビュー精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 153-161.

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