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2020

・Elucidating Monomer Character of an Alkenyl Boronate through Radical Copolymerization Leads to Copolymer Synthesis beyond the Limitation of Copolymerizability by Side-Chain Replacement
Makino, H.; Nishikawa, T.; Ouchi, M.
ACS Macro Lett., 2020, Accepted.


・Ring-Expansion Cationic Cyclopolymerization for Construction of Cyclic Cyclopolymers
Kubota, H.; Yoshida, S.; Ouchi, M.
Polym. Chem., 2020, Accepted.


・二種類のモノマー単位が交互につながった高分子 -環化重合による交互シークエンス共重合体の合成と配列機能-
大内 誠
化学, 2020, 75(6), 68-69.

・モノマー単位を高分子鎖内で精密に混ぜる -配列制御で拓く新しい高分子材料-
大内 誠
化学と工業, 2020, 73(5), 399-401.

・Design of a maleimide monomer to achieve precise sequence control and functionalization for an alternating copolymer with vinylphenol
Nishimori, K.; Ouchi, M.
Polym. J., 2020, Accepted.


・Selective Coupling and Polymerization of Folded Polymer Micelles to Nanodomain Self-Assemblies
Ommura, Y.; Imai, S.; Takenaka, M.; Ouchi, M.; Terashima, T.
ACS Macro Lett., 2020, 9(3), 426–430.
Selected as a front cover.


・AB-alternating copolymers via chain-growth polymerization: synthesis, characterization, self-assembly, and functions
Nishimori, K.; Ouchi, M.
Chem. Commun., 2020, 56(24), 3473–3483.
Selected as a inside cover.


・Unprecedented Sequence Control and Sequence‐Driven Properties in A Series of AB‐Alternating Copolymers Consisting Solely of Acrylamide Units
Kametani, Y.; Sawamoto, M.; Tournilhac, F.; Ouchi, M.
Angew. Chem. Int. Ed., 2020, 59(13), 5193–5201.
Press release from Kyoto University
Press release from JST


・Molecular Imprinting on Amphiphilic Folded Polymers for Selective Molecular Recognition in Water
Nagao, C.; Sawamoto, M.; Terashima, T.
J. Polym. Sci., 2020, 58(1), 215–224.


2019

・Unusual Radical Copolymerization of Suprabulky Methacrylate with N-Hydroxysuccinmide Acrylate: Facile Syntheses of Alternating-Rich Copolymers of Methacrylic Acid and N-Alkyl Acrylamide
Oh, D.; Furuya, Y.; Ouchi, M.
Macromolecules, 2019, 52(22), 8577–8586.


・両親媒性ランダム共重合体の自己組織化
寺島 崇矢
高分子, 2019, 68(9), 493-494.

・Self-assembly of amphiphilic block pendant polymers as microphase separation materials and folded flower micelles
Matsumoto, M.; Takenaka, M.; Sawamoto, M.; Terashima, T.
Polym. Chem., 2019, 10(36), 4954–4961.


・Controlled radical depolymerization of chlorine-capped PMMA via reversible activation of the terminal group by ruthenium catalyst
Sano, Y.; Konishi, T.; Sawamoto, M.; Ouchi, M.
Eur. Polym. J., 2019, 120, 109181.


・Polymethacrylic Acid Shows Thermoresponsivity in an Organic Solvent
Cazares-Cortes, E.; Baker, C. B.; Nishimori, K.; Ouchi, M.; Tournilhac, F.
Macromolecules, 2019, 52(15), 5995–6004.


・Design of Thermoresponsive Polymers Toward Antibody Purification
Nishimori, K.; Maruyama, M.; Shimazaki, Y.; Ouchi, M.; Yoshida, H.
ACS Appl. Polym. Mater., 2019, 1(8), 1925–1929.
Selected as a cover picture.


・An Alkenyl Boronate as a Monomer for Radical Polymerizations: Boron as a Guide for Chain Growth and as a Replaceable Side Chain for Post‐Polymerization Transformation
Nishikawa, T.; Ouchi, M.
Angew. Chem. Int. Ed., 2019, 58(36), 12435–12439.
Selected as a "Hot Paper."


・Physical gelation of AB-alternating copolymers made of vinyl phenol and maleimide units: cooperation between precisely incorporated phenol and long alkyl pendant groups
Nishimori, K.; Cazares-Cortes, E.; Guigner, J.-M.; Tournilhac, F.; Ouchi, M.
Polym. Chem., 2019, 10(18), 2327–2336.


・Orthogonal Folding of Amphiphilic/Fluorous Random Block Copolymers for Double and Multicompartment Micelles in Water
Matsumoto, M.; Sawamoto, M.; Terashima, T.
ACS Macro Lett., 2019, 8(3), 320–325.


・Precise control of single unit monomer radical addition with a bulky tertiary methacrylate monomer toward sequence-defined oligo- or poly(methacrylate)s via the iterative process
Oh, D.; Sawamoto, M.; Ouchi, M.
Polym. Chem., 2019, 10(16), 1998–2003.
Selected as a cover picture.
Selected as the paper of the month.


・Self-Sorting of Amphiphilic Copolymers for Self-Assembled Materials in Water: Polymers Can Recognize Themselves
Imai, S.; Takenaka, M.; Sawamoto, M.; Terashima, T.
J. Am. Chem. Soc., 2019, 141(1), 511–519.

2018_Imai_JACS


・Amphiphilic Fluorous Random Copolymer Self-Assembly for Encapsulation of a Fluorinated Agrochemical
Ko, H. J.; Bhattacharya, A.; Terashima, T.; Sawamoto, M.; Maynard, D. H.
J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 532–539.


・Design of Maleimide Monomer for Higher Level of Alternating Sequence in Radical Copolymerization with Styrene
Nishimori, K.; Sawamoto, M.; Ouchi, M.
J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 367–375.


2018

・環拡大カチオン重合による環状ポリマーの精密合成
大内 誠
環状高分子の合成と機能発現, 監修:手塚 育志, シーエムシー出版, 2018, pp. 47–56.

・配列制御ポリマーと環状ポリマーの精密合成:配列とトポロジーが温度応答性に与える影響
大内 誠
刺激応答性高分子 ハンドブック, 監修:宮田 隆志, シーエムシー出版, 2018, pp. 49–54.

・ランダム共重合体を基盤とするミセル構築とナノ構造体の創出
寺島 崇矢
ブロック共重合体の構造制御と応用展開, 監修:竹中幹人, シーエムシー出版, 2018, pp. 101–116.

・原子移動ラジカル重合によるシークエンス制御
大内 誠
リビングラジカル重合 −機能性高分子の合成と応用展開−, 監修:松本章一, シーエムシー出版, 2018, pp. 18–26.

・リビングラジカル重合による両親媒性ポリマーの合成と精密ナノ会合体の創出
寺島 崇矢
リビングラジカル重合 −機能性高分子の合成と応用展開−, 監修:松本章一, シーエムシー出版, 2018, pp. 146–157.

・Control of Alternating Sequence for N-isopropylacrylamide (NIPAM) and Methacrylic Acid (MAA) Units in Copolymer via Cyclopolymerization and Transformation of the Cyclopendant
Kametani, Y.; Sawamoto, M.; Ouchi, M.
Angew. Chem. Int. Ed., 2018, 57(34), 10905–10909.
Press release from Kyoto University.


・Self-Assembly of Amphiphilic ABA Random Triblock Copolymers in Water
Kozawa,K. S.; Matsumoto, K.; Suzuki, A.; Sawamoto, M.; Terashima, T.
J. Polym. Sci. Part A: Polym. Chem., 2018, 57, 313–321.


・Acrylate-Selective Transesterification of Methacrylate/Acrylate Copolymers: Postfunctionalization with Common Acrylates and Alcohols
Ito, D.; Ogura, Y.; Sawamoto, M.; Terashima, T.
ACS Macro Lett., 2018, 7(8), 997–1002.


・Programmed Self-Assembly of Amphiphilic Random Copolymers in Water via Controlled Radical Polymerization
Terashima, T.
ACS Symp. Ser., 2018, 1285, 143–155.

・Nanostructured Materials via the Pendant Self-Assembly of Amphiphilic Crystalline Random Copolymers
Hattori, G.; Takenaka, M.; Sawamoto, M.; Terashima, T.
J. Am. Chem. Soc., 2018, 140(27), 8376–8379.


・Intramolecular Folding or Intermolecular Self-Assembly of Amphiphilic Random Copolymers: On-Demand Control by Pendant Design
Shibata, M.; Matsumoto, M.; Hirai, Y.; Takenaka, M.; Sawamoto, M.; Terashima, T.
Macromolecules, 2018, 51(10), 3738–3745.


・Fluorous Gradient Copolymers via in-Situ Transesterification of a Perfluoromethacrylate in Tandem Living Radical Polymerization: Precision Synthesis and Physical Properties
Ogura, Y.; Takenaka, M.; Sawamoto, M.; Terashima, T.
Macromolecules, 2018, 51(3), 864–871.


・Programmed Self-Assembly Systems of Amphiphilic Random Copolymers into Size-Controlled and Thermoresponsive Micelles in Water
Imai, S.; Hirai, Y.; Nagao, C.; Sawamoto, M.; Terashima, T.
Macromolecules, 2018, 51(2), 398–409.


・Sequence Regulation in Chain-Growth Polymerizations
Ouchi, M.
Wiley, Lutz, J.-F. (ed), Sequence‐Controlled Polymers, 2018, pp 257–279.

・Sequence-controlled polymers via reversible-deactivation radical polymerization
Ouchi, M.; Sawamoto, M.
Polym. J., 2018, 50(1), 83–94.


2017

・Expanding vinyl ether monomer repertoire for ring‐expansion cationic polymerization: Various cyclic polymers with tailored pendant groups
Kammiyada, H.; Ouchi, M.; Sawamoto, M.
J. Polym. Sci. Part A: Polym. Chem. 2017, 55(18), 3082-3089.

・Fluorous Comonomer Modulates the Reactivity of Cyclic Ketene Acetal and Degradation of Vinyl Polymers
Ko, H, J.; Terashima, T.; Sawamoto, M.; Maynard, D. H.
Macromolecules, 2017, 50(23), 9222-9232.

・Self-assembly of PEG/dodecyl-graft amphiphilic copolymers in water: consequences of the monomer sequence and chain flexibility on uniform micelles
Hattori, G.; Hirai, Y.; Sawamoto, M.; Terashima, T.
Polym. Chem., 2017, 8(46), 7248-7259.

・Cyclopolymerization of Cleavable Acrylate-Vinyl Ether Divinyl Monomer via Nitroxide-Mediated Radical Polymerization: Copolymer beyond Reactivity Ratio
Kametani, Y.; Nakano, M.; Yamamoto, T.; Ouchi, M.; Sawamoto, M.
ACS Macro Lett., 2017, 6, 754−757.


・Self-Folding Polymer Iron Catalysts for Living Radical Polymerization
Azuma, Y.; Terashima, T.; Sawamoto, M.
ACS Macro Lett., 2017, 6, 830-835.


・Single-Chain Nanoparticles via Self-Folding Amphiphilic Copolymers in Water
Terashima, T.; Sawamoto, M.
Wiley, Pomposo, J. A. (ed), Single-Chain Polymer Nanoparticles: Synthesis, Characterization, Simulations and Applications, 2017, pp 313-339.

・両親媒性ランダムコポリマーの自己組織化:一次構造制御による精密ナノ会合体の創出
寺島 崇矢、澤本 光男
高分子論文集, 2017, 74(4), 265-277.

・Self-Assembly of Amphiphilic Random Copolyacrylamides into Uniform and Necklace Micelles in Water
Kimura, Y.; Terashima, T.; Sawamoto, M.
Macromol. Chem. Phys., 2017, 218(18), 1700230.

・Compartmentalization Technologies via Self-Assembly and Cross-Linking of Amphiphilic Random Block Copolymers in Water
Matsumoto, M.; Terashima, T.; Matsumoto, K.; Takenaka, M.; Sawamoto, M.
J. Am. Chem. Soc. 2017, 139, 7164-7167.


・Synthesis of Fluorinated Gradient Copolymers via In Situ Transesterification with Fluoroalcohols in Tandem Living Radical Polymerization
Ogura, Y.; Terashima, T.; Sawamoto, M.
Polym. Chem., 2017, 8, 2299-2308. (Inside Front Cover)

・Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification
Ogura, Y.; Artar, M.; Palmans, A. R. A.; Sawamoto, M.; Meijer, E. W.; Terashima, T.
Macromolecules, 2017, 50, 3215-3223.

・Microgel Star Polymer Catalysts as Active and Functional Nanoreactors for Organic Reactions and Polymerizations
Terashima, T.; Sawamoto, M.
Springer, Poli (ed), Effects of Nanoconfinement on Catalysis, Fundamental and Applied Catalysis, 2017, 125-146.

・A Study on Physical Properties of Cyclic Poly(vinyl ether)s Synthesized via Ring-Expansion Cationic Polymerization
Kammiyada, H.; Ouchi, M.; Sawamoto, M.
Macromolecules, 2017, 50, 841-848.

・Amphiphilic PEG-Functionalized Gradient Copolymers via Tandem Catalysis of Living Radical Polymerization and Transesterification
Ogura, Y.; Terashima, T.; Sawamoto, M.
Macromolecules, 2017, 50, 822-831.

・Precision Synthesis of Imine-Functionalized Reversible Microgel Star Polymers via Dynamic Covalent Cross-Linking of Hydrogen-Bonding Block Copolymer Micelles
Azuma, Y.; Terashima, T.; Sawamoto, M.
Macromolecules, 2017, 50, 587-596.

2016

・リビングラジカル重合をすべての人に
寺島 崇矢
化学, 2016, 71(12), 62-63

・Periodic Introduction of Hamilton Receptor into Polystyrene Backbone for Supramolecular Graft Copolymer with Regular Interval
Lee, S.; Ouchi, M.; Kim, S.; Sawamoto, M.
Polym. Chem., 2016, 7, 7152-7160.

・Amphiphilic Random Copolymers with Hydrophobic/Hydrogen- Bonding Urea Pendants: Self-Folding Polymers in Aqueous and Organic Media
Matsumoto, K.; Terashima, T.; Sugita, T.; Takenaka, M.; Sawamoto, M.
Macromolecules, 2016, 49, 7917−7927.

・A Convergent Approach to Ring Polymers with Narrow Molecular Weight Distributions through Post Dilution in Ring Expansion Cationic Polymerization
Kammiyada, H.; Ouchi, M.; Sawamoto, M.
Polym. Chem., 2016, 7, 6911-6917.

・Alternating Sequence Control for Carboxylic Acid and Hydroxy Pendant Groups via Controlled Radical Cyclopolymerization of a Divinyl Monomer Carrying a Cleavable Spacer
Ouchi, M.; Nakano, M.; Nakanishi, T.; Sawamoto, M.
Angew. Chem. Int. Ed., 2016, DOI: 10.1002/ange.201607169

・Ferrocene Cocatalysis for Ruthenium-Catalyzed Radical Miniemulsion Polymerization
Bultz, E.; Ouchi, M.; Fujimura, K.; Sawamoto, M.; Cunningham, M.F.
Polymer, 2016, DOI: 10.1016/j.polymer.2016.08.084

・Living CO2-Switchable Latexes Prepared via Emulsion ATRP and AGET Miniemulsion ATRP
Su, X.; Nishizawa, K.; Bultz, E.; Sawamoto, M.; Ouchi, M.; Jessop, P.G.; Cunningham, M.F.
Macromolecules, 2016, 49, 6251-6259.

・Sequence Analysis for Alternating Copolymers by MALDI‐TOF‐MS: Importance of Initiator Selectivity for Comonomer Pair
Nishimori, K.; Ouchi, M.; Sawamoto, M.
Macromol. Rapid. Commun., 2016, 37, 1414–1420.
Selected as Back Cover

・精密ラジカル重合による機能性高分子
寺島 崇矢、澤本 光男
高分子, 2016, 65(9), 503-505

・Polyacrylamide Pseudo Crown Ethers via Hydrogen Bond-Assisted Cyclopolymerization
Kimura,Y.; Miyabara, Y.; Terashima, T.; Sawamoto, M.
J. Polym. Sci. Part A: Polym. Chem. 2016, 54, 3294-3302.

・Precision Self-Assembly of Amphiphilic Random Copolymers into Uniform and Self-Sorting Nanocompartments in Water
Hirai, Y.; Terashima, T.; Takenaka, M.; Sawamoto, M.
Macromolecules 2016, 49, 5084-5091.

・Protein Storage with Perfluorinated PEG Compartments in a Hydrofluorocarbon Solvent
Koda, Y.; Terashima, T.; Maynard. H. D.; Sawamoto, M.
Polym. Chem. 2016, 7, 6694-6698.

・Multimode Self-Folding Polymers via Reversible and Thermoresponsive Self-Assembly of Amphiphilic/Fluorous Random Copolymers
Koda, Y.; Terashima, T.; Sawamoto, M.
Macromolecules 2016, 49, 4534-4543.

・Iterative Radical Addition with a Special Monomer Carrying Bulky and Convertible Pendant: A New Concept toward Controlling the Sequence for Vinyl Polymers
Oh, D.; Ouchi, M.; Nakanishi, T.; Ono, H.; Sawamoto, M.
ACS Macro Lett. 2016, 5, 745-749.

・Terminal-Selective Transesterification of Chlorine-Capped Poly(Methyl Methacrylate)s: A Modular Approach to Telechelic and Pinpoint-Functionalized Polymers
Ogura, Y.; Terashima, T.; Sawamoto, M.
J. Am. Chem. Soc. 2016, 138, 5012-5015.

・Cationic Cp*–Ruthenium Catalysts for Metal-Catalyzed Living Radical Polymerization: Cocatalyst-Independent Catalysis Tuned by Counteranion
Fujimura, K.; Ouchi, M.; Tsujita, J.; Sawamoto, M.
Macromolecules 2016, 49, 2962-2970.

・A Strategy for Sequence Control in Vinyl Polymers via Iterative Controlled Radical Cyclization
Hibi, Y.; Ouchi, M.; Sawamoto, M.
Nature Commun. 2016, 7, 11064.(DOI: 10.1038/ncomms11064.) プレス1(JST) プレス2(京都大学) 紹介記事

・Design of a hydrophilic ruthenium catalyst for metal-catalyzed living radical polymerization: highly active catalysis in water
Nishizawa, K.; Ouchi, M.; Sawamoto, M.
RSC Adv. 2016, 6, 6577-6582.

・Discussion on “Aperiodic Copolymers”
Rowan, S.J.; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Robert B Grubbs, R.B.; Hillmyer, M.A.; Hutchings, L.R., Mahanthappa, M. K.; Moatsou, D.; O’Reilly, R.K.; Ouchi, M.; Sawamoto, M.; Lodge, T.P.
ACS Macro Lett. 2016, 5, 1–3.

・リビング重合とは:総論
澤本 光男
CSJ カレントレビュー 精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 14-19.

・ラジカル重合(2):金属触媒
大内 誠
CSJ カレントレビュー 精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 63-74.

・星型ポリマー
金岡 鐘局,寺島 崇矢
CSJ カレントレビュー 精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 144-152.

・連鎖制御ポリマー
大内 誠
CSJ カレントレビュー 精密重合が拓く高分子合成―高度な制御と進む実用化, 日本化学会編, 化学同人, 2016, pp. 153-161.

 

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